Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling-Reference-Cited by-同舟云学术

Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling

Published:2021 Issue:31 Volume:12 Page:10483-10500
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Senft Laura¹²³⁴^ORCID,Moore Jamonica L.⁵⁶⁷⁸,Franke Alicja¹²³⁴^ORCID,Fisher Katherine R.¹²³⁴^ORCID,Scheitler Andreas⁹¹⁰¹¹⁴^ORCID,Zahl Achim⁹¹⁰¹¹⁴,Puchta Ralph⁹¹⁰¹¹⁴^ORCID,Fehn Dominik⁹¹⁰¹¹⁴^ORCID,Ison Sidney⁵⁶⁷⁸,Sader Safaa⁵⁶⁷⁸,Ivanović-Burmazović Ivana¹²³⁴^ORCID,Goldsmith Christian R.⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. Ludwig-Maximilian-University

3. D 81377 Munich

4. Germany

5. Department of Chemistry and Biochemistry

6. Auburn University

7. Auburn

8. USA

9. Department of Chemistry and Pharmacy

10. Friedrich-Alexander University Erlangen-Nuremberg

11. 91058 Erlangen

Abstract

Manganese complexes with polydentate quinol-containing ligands are found to catalyze the degradation of superoxide through inner-sphere mechanisms. The redox activity of the ligand stabilizes higher-valent manganese species.

Funder

Auburn University

National Science Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02465E

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