Synthesis and physico-chemical properties of the first water soluble Cu(ii)@hemicryptophane complex
Author:
Affiliation:
1. Laboratoire de Chimie
2. École Normale Supérieure de Lyon
3. CNRS
4. UCBL
5. F-69364 Lyon
6. Laboratoire de Résonances Magnétiques
7. CEA-Grenoble/INAC/SCIB/LRM
8. UMR-E 3 CEA-UJF
9. Grenoble Cedex 09
10. France
Abstract
A water-soluble metallo-enzyme model featuring a copper(ii) site encaged in a closed-shell cavity of a hemicryptophane has been synthesized and studied.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02085E
Reference39 articles.
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2. Synthesis and Study of Calix[6]cryptamides: A New Class of Heteroditopic Receptors that Display Versatile Host–Guest Properties Toward Neutral Species and Organic Associated Ion-Pair Salts
3. The Cooperative Effect in Ion-Pair Recognition by a Ditopic Hemicryptophane Host
4. Hydrogen Bonding-Directed Quantitative Self-Assembly of Cyclotriveratrylene Capsules and Their Encapsulation of C60 and C70
5. Exclusive enantioselective recognition of glucopyranosides by inherently chiral hemicryptophanes
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