Geometric requirements for living anionic polymerization: polymerization of rotationally constrained 1,3-dienes-Reference-Cited by-同舟云学术

Geometric requirements for living anionic polymerization: polymerization of rotationally constrained 1,3-dienes

Published:2022 Issue:38 Volume:13 Page:5478-5485
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Barent Ramona D.¹²,Wagner Manfred³,Frey Holger¹^ORCID

Affiliation:

1. Department of Chemistry, Johannes Gutenberg University, Duesbergweg 10-14, 55128 Mainz, Germany

2. Max Planck Graduate Center, Forum Universitatis 2, 55122 Mainz, Germany

3. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

Abstract

1,3-Dienes with prescribed cisoid geometry are capable of homo- and copolymerization with isoprene, whereas a transoid geometry prevents coordination with both double bonds, and hence no polymerization in cyclohexane occurs.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00999D

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