Synthesis of a well-defined alternating copolymer of 1,1-diphenylethylene and tert-butyldimethylsilyloxymethyl substituted styrene by anionic copolymerization: toward tailored graft copolymers with controlled side chain densities

Author:

Goseki Raita1234ORCID,Zhang Fan1234,Takahata Kazuki1234ORCID,Uchida Satoshi1234ORCID,Ishizone Takashi1234ORCID

Affiliation:

1. Department of Chemical Science and Engineering

2. Tokyo Institute of Technology

3. Tokyo 152-8552

4. Japan

Abstract

Well-defined alternating copolymers comprising 1,1-diphenylethylene (DPE) and styrene derivative having sterically bulky tert-butyldimethylsilyloxymethyl group at the meta position (St-TBS) were successfully synthesized.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference62 articles.

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3. T. Ishizone and A.Hirao , Anionic Polymerization: Recent Advances. In Synthesis of Polymers: New Structures and Methods , ed. D. Schlüter , C. J. Hawker and J. Sakamoto , Wiley-VCH , Singapore , 2012 , vol. 1 , pp. 81–133

4. Precise Synthesis of Macromolecular Architectures by Novel Iterative Methodology Combining Living Anionic Polymerization with Specially Designed Linking Chemistry

5. Polymers with Complex Architecture by Living Anionic Polymerization

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