On the variation of cluster core characteristics by an endohedral atom. Shape variation in 8-ce [EAu4(PPh3)4]2+ (E = N, P, As, Sb) clusters

Author:

Guajardo-Maturana Raul1ORCID,MacLeod Carey Desmond2ORCID,Rodríguez-Kessler Peter L.3,Muñoz-Castro Alvaro4ORCID

Affiliation:

1. Instituto de Investigación Interdisciplinar en Ciencias Biomédicas SEK (I3CBSEK) Chile, Universidad SEK, Santiago, Chile

2. Laboratorio de Química Inorgánica y Materiales Moleculares, Facultad de Ingenieria, Universidad Autónoma de Chile, Llano Subercaceaux 2801, San Miguel, Santiago, Chile

3. Centro de Investigaciones en Óptica A.C., Loma del Bosque 115, Col. Lomas del Campestre, León, Guanajuato, 37150, Mexico

4. Facultad de Ingeniería, Arquitectura y Diseño, Universidad San Sebastián, Bellavista 7, Santiago, 8420524, Chile

Abstract

Atomically precise gold superatoms have attracted interest owing to their suitable use as building blocks for cluster-assembled materials, favoring ordered structures with advanced properties.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

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