On the halide aggregation into the [Au4(PPh3)4]4+ cluster core. Insights from structural, optical and interaction energy analysis in [(Ph3PAu)4X2]2+ and [(Ph3PAu)4X]3+ species (X = Cl−, Br−, I−)-Reference-Cited by-同舟云学术

On the halide aggregation into the [Au₄(PPh₃)₄]⁴⁺ cluster core. Insights from structural, optical and interaction energy analysis in [(Ph₃PAu)₄X₂]²⁺ and [(Ph₃PAu)₄X]³⁺ species (X = Cl⁻, Br⁻, I⁻)

Published:2024 Issue:27 Volume:26 Page:18828-18836
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guajardo-Maturana Raul¹^ORCID,Rodríguez-Kessler Peter. L.²,Muñoz-Castro Alvaro³^ORCID

Affiliation:

1. Universidad SEK, Facultad de Ciencias de la Salud, Instituto de Investigación Interdisciplinar en Ciencias Biomédicas SEK (I3CBSEK) Chile, Fernando Manterola 0789, Providencia, Santiago, Chile

2. Centro de Investigaciones en Óptica A.C., Loma del Bosque 115, Col. Lomas del Campestre, León, Guanajuato, 37150, Mexico

3. Facultad de Ingeniería, Arquitectura y Diseño, Universidad San Sebastián, Bellavista 7, Santiago, 8420524, Chile

Abstract

The aggregation of halide atoms into gold clusters offers an interesting scenario for the development of novel metal-based cavities for anion recognition and sensing applications.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01467G

Reference117 articles.

1. C. N. R.Rao , A.Müller and A. K.Cheetham , The Chemistry of Nanomaterials , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, FRG , 2004

2. Shape-Controlled Synthesis of Gold and Silver Nanoparticles

3. The chemistry of functional nanomaterials

4. Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

5. Precise synthesis, functionalization and application of thiolate-protected gold clusters