A chemical dynamics study of the reaction of the methylidyne radical (CH, X2Π) with dimethylacetylene (CH3CCCH3, X1A1g)-Reference-Cited by-同舟云学术

A chemical dynamics study of the reaction of the methylidyne radical (CH, X2Π) with dimethylacetylene (CH3CCCH3, X1A1g)

Published:2022 Issue:1 Volume:24 Page:578-593
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

He Chao¹^ORCID,Fujioka Kazuumi¹,Nikolayev Anatoliy A.²³^ORCID,Zhao Long¹,Doddipatla Srinivas¹,Azyazov Valeriy N.²³,Mebel Alexander M.⁴^ORCID,Sun Rui¹^ORCID,Kaiser Ralf I.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Hawai’i at Manoa, Honolulu, Hawaii 96822, USA

2. Lebedev Physical Institute, Samara 443011, Russia

3. Samara National Research University, Samara 443086, Russia

4. Department of Chemistry and Biochemistry, Florida International University, Miami, Florida 33199, USA

Abstract

Center-of-mass flux contour map for the reaction of the methylidyne (CH; X2Π) radical with dimethylacetylene (CH3CCCH3; X1A1g) leading to the formation of 1-methyl-3-methylenecyclopropene (13%) and 1-penten-3-yne (81%).

Funder

Ministry of Science and Higher Education of the Russian Federation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04443E

Reference115 articles.

1. The identification of channel three in isolated benzene

2. Laser photolysis of benzene. V. Formation of hot benzene