Cyclization or bridging: which occurs faster is the key to the self-assembly mechanism of Pd6L3 coordination prisms-Reference-Cited by-同舟云学术

Cyclization or bridging: which occurs faster is the key to the self-assembly mechanism of Pd6L3 coordination prisms

Published:2022 Issue:5 Volume:24 Page:2997-3006
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhang Xinman¹,Takahashi Satoshi¹^ORCID,Aratsu Keisuke¹,Kikuchi Isamu¹,Sato Hirofumi²³⁴^ORCID,Hiraoka Shuichi¹^ORCID

Affiliation:

1. Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan

2. Department of Molecular Engineering, Kyoto University, Kyoto 615-8510, Japan

3. Elements Strategy Initiative for Catalysts and Batteries, Kyoto University, Kyoto 615-8510, Japan

4. Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan

Abstract

QASAP and NASAP reveal that the macrocyclization faster than the bridging reaction in the intermediate leads to the Pd6L3 coordination prisms, while kinetically trapped species are produced when the bridging reaction takes place faster.

Funder

Japan Society for the Promotion of Science

Asahi Glass Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04448F

Reference68 articles.

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5. Triangular and Tetrahedral Array of Silver(I) Ions by a Novel Disk-Shaped Tridentate Ligand: Dynamic Control of Coordination Equilibrium of the Silver(I) Complexes

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