NMR study of Li distribution in Li7−xHxLa3Zr2O12 garnets
Author:
Affiliation:
1. Instituto de Ciencia de Materiales de Aragón
2. CSIC–Universidad de Zaragoza
3. E-50009 Zaragoza
4. Spain
5. Instituto de Ciencia de Materiales de Madrid
6. CSIC
7. E-28049 Madrid
Abstract
We present a NMR investigation of 6Li7−xHxLa3Zr2O12 (0 ≤ x ≤ 5) garnets to study the distribution of Li ions. The facile H+/Li+ exchange alters the relative population of Li sites, and allows the identification of 3 different bands ascribed to Li in different environments. Variable temperature measurements indicated the presence of dynamic processes between octahedral and tetrahedral Li sites.
Funder
Consejo Superior de Investigaciones Científicas
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/TA/C4TA04570J
Reference51 articles.
1. Garnet-type solid-state fast Li ion conductors for Li batteries: critical review
2. Synthesis and structure analysis of tetragonal Li7La3Zr2O12 with the garnet-related type structure
3. Cation ordering in Li containing garnets: synthesis and structural characterisation of the tetragonal system, Li7La3Sn2O12
4. Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
5. Crystal Chemistry and Stability of “Li7La3Zr2O12” Garnet: A Fast Lithium-Ion Conductor
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