Evolution of boron clusters in iron tetraborides under high pressure: semiconducting and ferromagnetic superhard materials
Author:
Affiliation:
1. Key Laboratory of Materials Modification by Laser
2. Ion and Electron Beams (Dalian University of Technology)
3. Ministry of Education
4. Dalian 116024
5. China
Abstract
The building block of the FeB4 compound transforms from a corrugated B6 ring to an unusual B4 tetrahedron and finally to a cubooctahedral B12 cluster under pressure. The latter two are predicted as superhard semiconductor or superhard magnetic materials.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA05852J
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5. J. Hoard , R.Hughes and E.Muetterties, The chemistry of boron and its compounds, Wiley, New York, 1967, p. 59
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