N,N′-Dialkyl-N,N′-diaryl-1,10-phenanthroline-2,9-dicarboxamides as donor ligands for separation of rare earth elements with a high and unusual selectivity. DFT computational and experimental studies-Reference-Cited by-同舟云学术

N,N′-Dialkyl-N,N′-diaryl-1,10-phenanthroline-2,9-dicarboxamides as donor ligands for separation of rare earth elements with a high and unusual selectivity. DFT computational and experimental studies

Published:2015 Issue:35 Volume:51 Page:7466-7469
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ustynyuk Yu. A.¹²³⁴,Borisova N. E.¹²³⁴,Babain V. A.⁵⁶⁴,Gloriozov I. P.¹²³⁴,Manuilov A. Y.¹²³⁴,Kalmykov S. N.¹²³⁴,Alyapyshev M. Yu.⁵⁶⁴⁷⁸,Tkachenko L. I.⁷⁸⁴,Kenf E. V.⁷⁸⁴,Ustynyuk N. A.⁹¹⁰¹¹⁴

Affiliation:

1. Department of Chemistry

2. M.V. Lomonosov Moscow State University

3. Moscow 119991

4. Russia

5. ITMO University

6. St. Petersburg

7. Khlopin Radium Institute

8. St. Petersburg 194021

9. A.N. Nesmeyanov Institute of Organoelement Compounds

10. Russian Academy of Sciences

11. Moscow 119334

Abstract

These diamides were predicted (DFT simulation) and then were proved to be efficient donor ligands for the separation of lanthanides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC01620G

Reference34 articles.

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2. 17 Scandium, yttrium, the lanthanides and the actinides

3. Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands

4. Thermodynamics of lanthanide(III) complexation in non-aqueous solvents

5. A Comparative Study of Ionic Liquids and a Conventional Organic Solvent on the Extraction of Rare-earth Ions with TOPO

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