Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen
Author:
Affiliation:
1. Centre for Hyperpolarization in Magnetic Resonance
2. University of York
3. York Science Park
4. York
5. UK
6. Department of Chemistry
Abstract
Reaction of [Ir(IMes)(COD)Cl] with pyridazine (pdz) or phthalazine (phth) and H2 results in the formation of the para-hydrogen magnetisation transfer catalysts [Ir(H)2(IMes)(pdz)3]Cl and [Ir(H)2(IMes)(phth)3]Cl.
Funder
Wellcome Trust
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00756A
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