Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates-Reference-Cited by-同舟云学术

Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

Published:2014 Issue:35 Volume:50 Page:4554-4557
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Ohmatsu Kohsuke¹²³⁴⁵,Ito Mitsunori¹²³⁴⁵,Ooi Takashi¹²³⁴⁵

Affiliation:

1. Institute of Transformative Bio-Molecules (WPI-ITbM)

2. and Department of Applied Chemistry

3. Graduate School of Engineering

4. Nagoya University

5. Nagoya 464-8603, Japan

Abstract

The first highly E- and enantioselective allylic alkylation of prochiral carbon nucleophiles with 1,2-disubstituted allylic carbonates is reported. The key is the ability of modular ion-paired chiral ligands to simultaneously control the E/Z selectivity and enantioselectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC49338E

Reference76 articles.

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4. Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion

5. Enantio- and Diastereodivergent Dual Catalysis: α-Allylation of Branched Aldehydes

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