Rational enhancement of the energy barrier of bis(tetrapyrrole) dysprosium SMMs via replacing atom of porphyrin core-Reference-Cited by-同舟云学术

Rational enhancement of the energy barrier of bis(tetrapyrrole) dysprosium SMMs via replacing atom of porphyrin core

Published:2015 Issue:10 Volume:6 Page:5947-5954
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cao Wei¹²³⁴⁵,Gao Chen⁶⁷⁸⁴⁵,Zhang Yi-Quan⁹¹⁰¹¹¹²⁵,Qi Dongdong¹²³⁴⁵,Liu Tao¹³¹⁴¹⁵⁵,Wang Kang¹²³⁴⁵,Duan Chunying¹³¹⁴¹⁵⁵,Gao Song⁶⁷⁸⁴⁵,Jiang Jianzhuang¹²³⁴⁵

Affiliation:

1. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials

2. Department of Chemistry

3. University of Science and Technology Beijing

4. Beijing

5. China

6. Beijing National Laboratory of Molecular Science State Key Laboratory of Rare Earth Materials Chemistry and Applications

7. College of Chemistry and Molecular Engineering

8. Peking University

9. Jiangsu Key Laboratory for NSLSCS

10. School of Physical Science and Technology

11. Nanjing Normal University

12. Nanjing 210023

13. State Key Laboratory of Fine Chemicals

14. Dalian University of Technology

15. Dalian

Abstract

Replacing a porphyrin N atom induces higher electrostatic environment anisotropy around the Dy center, giving the highest energy barrier among bis(tetrapyrrole) Dy SMMs.

Funder

National Natural Science Foundation of China

Beijing Municipal Commission of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02314A

Reference104 articles.

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2. Quantum Hysteresis in Molecular Magnets