Nitrate anions embedded in rigid and cationic 3D energetic MOFs constructed by the chelating ligand towards insensitive energetic materials

Author:

Wang Qin1,Yan Yun-Fan23,Weng Jiao-Lin1,Huang Ying1,Yang Fu1,Xie Hao-Hui1,Tan Fei1,Zheng Fa-Kun123ORCID,Xu Jian-Gang123ORCID

Affiliation:

1. College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, China

2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

3. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian 350108, P. R. China

Abstract

A rigid cationic 3D EMOF was prepared by a simple hydrothermal method using a nitrogen-rich chelating ligand, and a strong hydrogen bond interaction was formed to stabilize NO3 anions with high energy and low mechanical stimulation.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Fujian Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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