Spontaneous disproportionation of lithium biphenyl in solution: a combined experimental and theoretical study-Reference-Cited by-同舟云学术

Spontaneous disproportionation of lithium biphenyl in solution: a combined experimental and theoretical study

Published:2018 Issue:7 Volume:42 Page:5168-5177
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Bondarchuk Sergey V.¹²³^ORCID,Carrera Manuel⁴⁵⁶,de la Viuda Mónica⁴⁵⁶,Guijarro Albert⁴⁵⁶^ORCID

Affiliation:

1. Department of Chemistry and Nanomaterials Science, Bogdan Khmelnitsky Cherkasy National University

2. 18031 Cherkasy

3. Ukraine

4. Departamento de Química Orgánica and Instituto Universitario de Síntesis Orgánica, Unidad asociada del CSIC, Universidad de Alicante

5. Alicante

6. Spain

Abstract

Spontaneous disproportionation of lithium biphenyl radical anion into a lithium biphenyl dianion plus neutral biphenyl, according to 2LiBiph ⇄ Li₂Biph + Biph, has been evidenced experimentally by UV-vis spectroscopy and backed up theoretically using TDDFT methods.

Funder

Generalitat Valenciana

Ministry of Education and Science of Ukraine

Universidad de Alicante

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04726F

Reference69 articles.

1. Forschungen auf dem Gebiete der alkaliorganischen Verbindungen. I. Über Produkte der Addition von Alkalimetal an mehrfache Kohlenstoff-Kohlenstoff-Bindungen

2. M. Ue , in Role Assigned Electrolytes: Additives, in Lithium-Ion Batteries , ed. M. Yoshio , R. J. Brodd and A. Kozawa , Springer Science + Business Media , LLC , 2009 , pp. 96–101

3. A review on electrolyte additives for lithium-ion batteries

4. A. Rinaldi , Y.Wang , K. S.Tan , O.Wijaya and R.Yazami , in Lithium-air batteries for medium- and large-scale energy storage, in Advances in Batteries for Medium- and Large-Scale Energy Storage , ed. C. Menictas , M. Skyllas-Kazacos , T. M. Lim , Elsevier Ltd , 1st edn, 2015 , vol. 395–396, p. 387

5. Hyperfine Structure and Electron Densities in Aromatic Free Radicals

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