The study of metal-free and palladium-catalysed synthesis of benzochromenes via direct C–H arylation using unactivated aryl benzyl ethers derived from essential oils as raw materials-Reference-Cited by-同舟云学术

The study of metal-free and palladium-catalysed synthesis of benzochromenes via direct C–H arylation using unactivated aryl benzyl ethers derived from essential oils as raw materials

Published:2017 Issue:9 Volume:4 Page:1736-1744
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ortiz Villamizar Marlyn C.¹²³⁴⁵^ORCID,Zubkov Fedor I.⁶⁷⁸⁹^ORCID,Puerto Galvis Carlos E.¹²³⁴⁵^ORCID,Vargas Méndez Leonor Y.¹⁰¹¹¹²,Kouznetsov Vladimir V.¹²³⁴⁵^ORCID

Affiliation:

1. Laboratorio de Química Orgánica y Biomolecular

2. CMN

3. Universidad Industrial de Santander

4. Parque Tecnológico Guatiguará

5. Piedecuesta 681011

6. Department of Organic Chemistry

7. Peoples’ Friendship University of Russia

8. Moscow

9. Russian Federation

10. Grupo de Investigaciones Ambientales para el Desarrollo Sostenible

11. Universidad Santo Tomás-Seccional Bucaramanga

12. Colombia

Abstract

The synthesis of 6H-benzo[c]chromenes, from phenol-rich essential oils, was studied through two approaches, establishing the Pd-approach as the most efficient protocol over the metal-free process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C7QO00232G

Reference68 articles.

1. Natural and Synthetic Chromenes, Fused Chromenes, and Versatility of Dihydrobenzo[h]chromenes in Organic Synthesis

2. Synthesis of benzochromenes and dihydrophenanthridines with helical motifs using Garratt–Braverman and Buchwald–Hartwig reactions

3. Synthesis of the Bioactive Benzochromenes Pulchrol and Pulchral, Metabolites ofBourreria pulchra

4. Antibacterial Cannabinoids from Cannabis sativa: A Structure−Activity Study

5. Antimitotic activity of methoxyconidiol, a meroterpene isolated from an ascidian

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