A comparative study of titanium complexes bearing 2-(arylideneamino)phenolates and 2-((arylimino)methyl)phenolates as catalysts for ring-opening polymerization of ε-caprolactone and l-lactide

Author:

Wu Ling-Jo1,Kottalanka Ravi Kumar2,Chu Yu-Ting13ORCID,Lin Zheng-Ian4,Chang Chun-Juei1,Ding Shangwu13,Chen Hsuan-Ying1356ORCID,Wu Kuo-Hui7,Chen Chih-Kuang4

Affiliation:

1. Department of Medicinal and Applied Chemistry, Drug Development and Value Creation Research Center, Kaohsiung Medical University, Kaohsiung, Taiwan, 80708, Republic of China

2. Department of Chemistry, School of Applied Science and Humanities, Vignan's Foundation for Science Technology and Research, Vadlamudi, Guntur, Andhra Pradesh 522213, India

3. Department of Chemistry, National Sun Yat-Sen University, Kaohsiung, Taiwan, 80424, Republic of China

4. Polymeric Biomaterials Laboratory, Department of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung 80424, Taiwan

5. Department of Medical Research, Kaohsiung Medical University Hospital, Kaohsiung 80708, Taiwan, Republic of China

6. National Pingtung University of Science and Technology, Pingtung 91201, Taiwan

7. Department of Chemistry, National Central University, Taoyuan, Taiwan, 32001, Republic of China

Abstract

Titanium complexes bearing 2-(arylideneamino)phenolates and 2-((arylimino)methyl)phenolates were synthesized, and their catalytic activities in the polymerization of ε-caprolactone and l-lactide were studied.

Funder

Department of Science and Technology, Ministry of Science and Technology

Kaohsiung Medical University

National Science and Technology Council

Publisher

Royal Society of Chemistry (RSC)

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