Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds-Reference-Cited by-同舟云学术

Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds

Published:2020 Issue:23 Volume:49 Page:7932-7937
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ruiz Cristina¹²³⁴^ORCID,Raya-Barón Álvaro¹²³⁴,Ortuño Manuel A.⁵⁶⁷⁴^ORCID,Fernández Ignacio¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Physics

2. Research centre CIAIMBITAL

3. 04120 Almería

4. Spain

5. Institute of Chemical Research of Catalonia (ICIQ)

6. The Barcelona Institute of Science and Technology (BIST)

7. 43007 Tarragona

Abstract

A combined computational and experimental approach demonstrates the accelerating role of deaggregation agents, especially HMPA, in the Li-catalysed hydrosilylation of acetophenone in THF solution under very mild conditions.

Funder

Agència de Gestió d’Ajuts Universitaris i de Recerca

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01540G

Reference65 articles.

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4. Bis(imino)pyridine Iron Complexes for Aldehyde and Ketone Hydrosilylation

5. Iron-Catalyzed Enantioselective Hydrosilylation of Ketones

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