Deciphering the morphology of transition metal carbonate cathode precursors-Reference-Cited by-同舟云学术

Deciphering the morphology of transition metal carbonate cathode precursors

Published:2024 Issue:21 Volume:12 Page:12835-12855
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Barai Pallab¹^ORCID,Wang Xiaoping²,Wolfman Mark³,Chen Jiajun²,Gutierrez Arturo²,Garcia Juan C.²,Wen Jianguo⁴^ORCID,Kinnibrugh Tiffany²,Fister Timothy T.²^ORCID,Iddir Hakim H.²^ORCID,Srinivasan Venkat⁵

Affiliation:

1. Applied Materials Division, Argonne National Laboratory, Lemont, IL 60439, USA

2. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA

3. Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA

4. Center for Nanoscale Materials, Argonne National Laboratory, Lemont, IL 60439, USA

5. ACCESS, Argonne National Laboratory, Lemont, IL 60439, USA

Abstract

Minimization of bulk and surface free energy acts as the driving force for precipitation of transition metal carbonates. Thermodynamically dominated precipitates form single crystals, and kinetically controlled deposits show spherical morphology.

Funder

Office of Energy Efficiency and Renewable Energy

Vehicle Technologies Office

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA08095A

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