Organotemplate-free synthesis of two open-framework metal borophosphates-Reference-Cited by-同舟云学术

Organotemplate-free synthesis of two open-framework metal borophosphates

Published:2015 Issue:39 Volume:44 Page:17100-17105
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Dan¹²³⁴⁵,Feng Yuquan⁶⁷⁸⁵,Liu Yunling¹²³⁴⁵,Zhang Yuan¹²³⁴⁵,Li Guanghua¹²³⁴⁵,Yuan Hongming¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

2. College of Chemistry

3. Jilin University

4. Changchun 130012

5. P.R. China

6. College of Chemistry and Pharmacy Engineering

7. Nanyang Normal University

8. Nanyang 473061

Abstract

Two new isostructural metal borophosphates, |K₂(H₂O)|[CoB₂P₃O₁₂(OH)] (1) and |K₂(H₂O)|[NiB₂P₃O₁₂(OH)] (2), have been hydrothermally synthesized by the “green” organotemplate-free route. Notably, the introduction of potassium ions in our synthetic system endows 1 and 2 with the K⁺ ion conductivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02637G

Reference37 articles.

1. Fe(H2O)2BP2O8·H2O, a First Zeotype Ferriborophosphate with Chiral Tetrahedral Framework Topology

2. Structural Chemistry of Borophosphates, Metalloborophosphates, and Related Compounds

3. Na2[VB3P2O12(OH)]·2.92H2O: A New Open-Framework Vanadium Borophosphate Containing Extra-Large 16-Ring Pore Openings and 128166 Super Cavities Synthesized by Using the Boric Acid Flux Method

4. Synthesis, structure and magnetic property of a new organo-templated mixed-valent iron(ii, iii) borophosphate

5. Synthesis, Structure, and Magnetic Property of a New Open-Framework Manganese Borophosphate, [NH4]4[Mn9B2(OH)2(HPO4)4(PO4)6]

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