Two non-identical twins in one unit cell: characterization of 34π aromatic core-modified octaphyrins, their structural isomers and anion bound complexes-Reference-Cited by-同舟云学术

Two non-identical twins in one unit cell: characterization of 34π aromatic core-modified octaphyrins, their structural isomers and anion bound complexes

Published:2019 Issue:23 Volume:10 Page:5911-5919
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ghosh Arindam¹²³⁴⁵^ORCID,Dash Syamasrit¹²³⁴⁵^ORCID,Srinivasan A.¹²³⁴⁵^ORCID,Suresh Cherumuttathu H.⁶⁷⁸⁹⁵^ORCID,Chandrashekar Tavarekere K.¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemical Sciences

2. National Institute of Science Education and Research (NISER)

3. HBNI

4. Bhubaneswar-752050

5. India

6. Inorganic and Theoretical Chemistry Section

7. Chemical Sciences and Technology Division

8. CSIR-National Institute of Interdisciplinary Science and Technology

9. Trivandrum-695019

Abstract

Two inseparable isomers A and B (non-identical twins) crystallize in a single unit cell. However, replacement of middle thiophene ring by selenophene ring results in crystallization of two molecules of isomer A (identical twins).

Funder

Department of Atomic Energy, Government of India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01633C

Reference43 articles.

1. “To Twist or Not to Twist”: Figure-of-Eight and Planar Structures of Octaphyrins

2. Proton-Coupled Redox Switching in an Annulated π-Extended Core-Modified Octaphyrin

3. Synthesis of (bis)Silicon Complexes of [38], [37], and [36]Octaphyrins: Aromaticity Switch and Stable Radical Cation