Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence-Reference-Cited by-同舟云学术

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Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence

Published:2024 Issue:9 Volume:53 Page:4291-4298
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hou Ting¹,Zhao Chen-Chen²,Bao Song-Song¹^ORCID,Zhai Zhi-Min¹,Zheng Li-Min¹^ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China

2. Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China

Abstract

The morphology of Gd(NO3)3/R-,S-AnempH2 assemblies is controlled by solvent. The spiral bundles (R-,S-1) are CPL active with asymmetric factor 2.8 times larger than that of crystals (R-,S-2), while spindle-shaped particles (R-,S-3) are CPL inactive.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03735E

Reference44 articles.

1. Controllable Synthesis of Metal-Organic Frameworks and Their Hierarchical Assemblies

2. Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications

3. Optimizing Hydrogen Storage in MOFs through Engineering of Crystal Morphology and Control of Crystal Size

4. Controlled Shape Evolution of Pure‐MOF 1D Microcrystals towards Efficient Waveguide and Laser Applications

5. Synthesis and real-time monitoring of the morphological evolution of luminescent Eu(TCPP) MOFs

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