Two types of nitrito support for μ4-oxido-bridged [Cu4] complexes: synthesis, crystal structures, magnetic properties and DFT analysis-Reference-Cited by-同舟云学术

Two types of nitrito support for μ4-oxido-bridged [Cu4] complexes: synthesis, crystal structures, magnetic properties and DFT analysis

Published:2015 Issue:13 Volume:44 Page:6107-6117
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pait Moumita¹²³⁴,Shatruk Michael⁵⁶⁷⁸,Lengyel Jeff⁵⁶⁷⁸,Gómez-Coca Silvia⁹¹⁰¹¹¹²,Bauzá Antonio¹³¹⁴¹⁵¹²,Frontera Antonio¹³¹⁴¹⁵¹²^ORCID,Bertolasi Valerio¹⁶¹⁷¹⁸¹⁹,Ray Debashis¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology

3. Kharagpur 721 302

4. India

5. Department of Chemistry & Biochemistry

6. Florida State University

7. Tallahassee

8. USA

9. Departament de Química Inorganica and Institut de Recerca de Química Teórica i Computacional

10. Universitat de Barcelona

11. E-08028 Barcelona

12. Spain

13. Departament de Química

14. Universitat de les Illes Balears

15. 07122 Palma

16. Dipartimento di Chimica e Centro di Strutturistica Diffrattometica

17. Università diFerrara

18. 44100 Ferrara

19. Italy

Abstract

In situ generated NO₂⁻ and externally added NO₂⁻ and AcO⁻ ions have been utilized for the isolation of μ₄-oxido-bridged Cu₄ aggregates showing magnetic coupling which can be rationalized by DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03224A

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4. New μ4-Oxido-Bridged Copper Benzoate Quasi-Tetrahedron and Bis-μ3-Hydroxido-Bridged Copper Azide and Copper Thiocyanate Stepped Cubanes: Core Conversion, Structural Diversity, and Magnetic Properties

5. New Phenoxido-Bridged Quasi-Tetrahedral and Rhomboidal [Cu4] Compounds Bearing μ4-Oxido or μ1,1-Azido Ligands: Synthesis, Chemical Reactivity, and Magnetic Studies

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