Phase stability and sodium-vacancy orderings in a NaSICON electrode

Author:

Wang Ziliang1,Park Sunkyu234,Deng Zeyu1ORCID,Carlier Dany34,Chotard Jean-Noël24,Croguennec Laurence34ORCID,Gautam Gopalakrishnan Sai5ORCID,Cheetham Anthony K.16ORCID,Masquelier Christian24ORCID,Canepa Pieremanuele17ORCID

Affiliation:

1. Department of Materials Science and Engineering, National University of Singapore, 9 Engineering Drive 1, 117575, Singapore

2. Laboratoire de Réactivité et de Chimie des Solides (LRCS), CNRS UMR 7314, Université de Picardie Jules Verne, 80039 Amiens Cedex, France

3. CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR CNRS 5026, Pessac, F-33600, France

4. RS2E, Réseau Français sur le Stockage Electrochimique de l'Energie, FR CNRS 3459, F-80039 Amiens Cedex 1, France

5. Department of Materials Engineering, Indian Institute of Science, Bengaluru, Karnataka, 560012, India

6. Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106, USA

7. Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 Singapore, Singapore

Abstract

We elucidate the complex thermodynamics of sodium (Na) intercalation into the sodium super-ionic conductor (NaSICON)-type electrode, NaxV2(PO4)3, for promising Na-ion batteries with high-power density.

Funder

National Research Foundation Singapore

Agence Nationale de la Recherche

Association Nationale de la Recherche et de la Technologie

Conseil Régional Aquitaine

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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