Amide versus amine ligand paradigm in the direct amination of alcohols with Ru-PNP complexes-Reference-Cited by-同舟云学术

Amide versus amine ligand paradigm in the direct amination of alcohols with Ru-PNP complexes

Published:2018 Issue:15 Volume:8 Page:3969-3976
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Pingen Dennis¹²³⁴⁵^ORCID,Choi Jong-Hoo²⁶⁷⁵,Allen Henry⁸⁹¹⁰¹¹¹²,Murray George⁸⁹¹⁰¹¹¹²,Ganji Prasad¹³¹⁴¹⁵¹⁶,van Leeuwen Piet W. N. M.¹⁷¹⁸¹⁹²⁰^ORCID,Prechtl Martin H. G.²⁶⁷⁵^ORCID,Vogt Dieter²¹²²²³²⁴⁵^ORCID

Affiliation:

1. Chemical Materials Science

2. Department of Chemistry

3. University of Konstanz

4. Konstanz

5. Germany

6. University of Cologne

7. 50939 Cologne

8. EaStCHEM

9. School of Chemistry

10. University of Edinburgh

11. Edinburgh EH9 3JJ

12. UK

13. Institute of Chemical Research of Catalonia (ICIQ)

14. The Barcelona Institute of Science and Technology

15. 43007 Tarragona

16. Spain

17. Laboratoire de Physique et Chimie de Nano-Objets

18. INSA

19. F-31077 Toulouse

20. France

21. Lehrstuhl Technische Chemie

22. Fakultät Bio- und Chemieingenieurwesen

23. Technische Universität Dortmund

24. D-44227 Dortmund

Abstract

Ruthenium complexes of PNP-ligands bearing secondary amines were found to be inactive in the alcohol amination with NH₃, while all complexes of homologous ligands bearing tertiary amines gave active catalysts!

Funder

H2020 European Research Council

Institut Català d'Investigació Química

Deutsche Forschungsgemeinschaft

Ministerium für Innovation, Wissenschaft und Forschung des Landes Nordrhein-Westfalen

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00869H

Reference31 articles.