Stepwise photosensitized C(sp3)–C(CO) bond cleavage and C–P bond formation of 1,3-dicarbonyls with arylphosphine oxides
Author:
Affiliation:
1. College of Chemistry and Molecular Engineering
2. Henan Key Laboratory of Chemical Biology and Organic Chemistry
3. Key Laboratory of Applied Chemistry of Henan Universities
4. Zhengzhou University
5. Zhengzhou 450052
Abstract
A visible-light-induced metal-free cascade radical reaction of chemoselective C–C bond cleavage with a C–P bond formation was discovered to obtain β-ketophosphine oxides.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00075E
Reference34 articles.
1. Direct C−H Phosphonylation of Electron-Rich Arenes and Heteroarenes by Visible-Light Photoredox Catalysis
2. Metal-Free, Visible-Light-Promoted Synthesis of 3-Phosphorylated Coumarins via Radical C−P/C−C Bond Formation
3. Photoredox Catalysis in Organophosphorus Chemistry
4. Visible-Light-Induced Cascade Reaction of Isocyanides and N-Arylacrylamides with Diphenylphosphine Oxide via Radical C–P and C–C Bond Formation
5. Metal-Free Visible-Light-Mediated Oxidative Cross-Coupling of Thiols with P(O)H Compounds Using Air as the Oxidant
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