Straightforward synthesis of chiral non-racemic α-boryl isocyanides-Reference-Cited by-同舟云学术

Straightforward synthesis of chiral non-racemic α-boryl isocyanides

Published:2021 Issue:30 Volume:19 Page:6687-6691
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Fini Francesco¹²³⁴^ORCID,Zanni Alessandro¹²³⁴,Introvigne Maria Luisa¹²³⁴⁵,Stucchi Mattia¹²³⁴,Caselli Emilia¹²³⁴^ORCID,Prati Fabio¹²³⁴^ORCID

Affiliation:

1. Department of Life Sciences

2. Università degli Studi di Modena e Reggio Emilia

3. Modena

4. Italy

5. International Doctorate School in Clinical and Experimental Medicine (CEM)

Abstract

A concise synthesis of chiral non-racemic α-boryl isocyanides is achieved. α-Ammonium boronates and N-formylamido boronic acid MIDA-esters were exploited as key intermediates.

Funder

Università Degli Studi di Modena e Reggio Emila

Fondazione Cassa di Risparmio di Modena

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00616A

Reference34 articles.

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2. Boronic acids: Preparation and Application in Organic Synthesis, Medicine and Materials , ed. D. G. Hall , Wiley , Weinheim , 2nd rev. edn, 2011

3. The versatility of boron in biological target engagement

4. .alpha.-Halo boronic esters: intermediates for stereodirected synthesis

5. Asymmetric synthesis with boronic esters

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