Vacuum ultraviolet photochemistry of the conformers of the ethyl peroxy radical-Reference-Cited by-同舟云学术

Vacuum ultraviolet photochemistry of the conformers of the ethyl peroxy radical

Published:2021 Issue:38 Volume:23 Page:22096-22102
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wen Zuoying¹,Lin Xiaoxiao¹^ORCID,Tang Xiaofeng¹^ORCID,Long Bo²^ORCID,Wang Chengcheng¹,Zhang Cuihong¹,Fittschen Christa³^ORCID,Yang Jiuzhong⁴^ORCID,Gu Xuejun¹,Zhang Weijun¹

Affiliation:

1. Laboratory of Atmospheric Physico-Chemistry, Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei, 230031 Anhui, China

2. School of Materials Science and Engineering, Guizhou Minzu University, Guiyang, 550025 Guizhou, China

3. University Lille, CNRS, UMR 8522, PC2A – Physicochimie des Processus de Combustion et de l’Atmosphère, F-59000 Lille, France

4. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029 Anhui, China

Abstract

C2H5O2 plus its gauche and trans conformers are studied using synchrotron-based VUV photoionization mass spectrometry and theoretical calculations, and it is found that the gauche conformer has favorable Franck–Condon factors in photoionization.

Funder

Bureau of International Cooperation, Chinese Academy of Sciences

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02655K

Reference32 articles.

1. Chemical kinetics of hydrocarbon ignition in practical combustion systems