Ultra-stable Pd ions at Al T1/T2 sites on a dealuminated Pd/beta passive NOxadsorber

Author:

Zhu Yi1,Wang Jun12,Wang Chen23,Wang Jianqiang1,Shen Gurong24ORCID,Shen Meiqing1256ORCID

Affiliation:

1. Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, P. R. China

2. National Rare Earth Catalysis Research Institute, Dongying 257000, PR China

3. School of Environmental and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, P. R. China

4. Institute of New Energy Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China

5. State Key Laboratory of Engines, Tianjin University, Tianjin 300072, PR China

6. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, PR China

Abstract

The oxalic-acid modified Pd/beta shows a more stable performance of NOxstorage due to its more stable Pd ions and more stable Al T1/T2 species when exposed to reducing agents or treated under hydrothermal conditions.

Funder

National Key Research and Development Program of China

Innovative Research Group Project of the National Natural Science Foundation of China

Young Elite Scientists Sponsorship Program by Tianjin

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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