Co-existence of ferro- and antiferromagnetic interactions in a hexanuclear mixed-valence CoIII2MnII2MnIV2 cluster sustained by a multidentate Schiff base ligand-Reference-Cited by-同舟云学术

Co-existence of ferro- and antiferromagnetic interactions in a hexanuclear mixed-valence CoIII2MnII2MnIV2 cluster sustained by a multidentate Schiff base ligand

Published:2019 Issue:31 Volume:48 Page:11862-11871
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Stetsiuk Oleh¹²³⁴⁵,Synytsia Valentyn⁶⁷⁸⁹,Petrusenko Svitlana R.⁶⁷⁸⁹,Kokozay Vladimir N.⁶⁷⁸⁹^ORCID,El-Ghayoury Abdelkrim¹²³⁴⁵^ORCID,Cano Joan¹⁰¹¹¹²¹³^ORCID,Lloret Francesc¹⁰¹¹¹²¹³^ORCID,Julve Miguel¹⁰¹¹¹²¹³^ORCID,Fleury Benoit¹⁴¹⁵¹⁶¹⁷^ORCID,Avarvari Narcis¹²³⁴⁵^ORCID

Affiliation:

1. MOLTECH-Anjou

2. UMR 6200

3. CNRS

4. UNIV Angers

5. 49045 ANGERS Cedex

6. Department of Inorganic Chemistry

7. Taras Shevchenko National University of Kyiv

8. Kyiv 01601

9. Ukraine

10. Instituto de Ciencia Molecular (ICMol)/Departament de Química Inorgànica

11. Universitat de València

12. 46980 Paterna

13. Spain

14. Sorbonne Université

15. CNRS. Institut Parisien de Chimie Moléculaire

16. F-75005 Paris

17. France

Abstract

An unprecedented mixed-valence CoIII2MnII2MnIV2 cluster has been synthesized. Magnetochemical investigations combined with DFT calculations demonstrate the co-existence of antiferro- and ferromagnetic interactions within the MnIV2MnII2 core.

Funder

Centre National de la Recherche Scientifique

Universite Angers

Ministry of Education and Science of Ukraine

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02503K

Reference66 articles.