Solventless mechanochemical metallation of porphyrins-Reference-Cited by-同舟云学术

Solventless mechanochemical metallation of porphyrins

Published:2017 Issue:1 Volume:19 Page:102-105
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Ralphs Kathryn¹²³⁴,Zhang Chen¹²³⁴,James Stuart L.¹²³⁴

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Queens University Belfast

3. Belfast

4. UK

Abstract

We demonstrate solvent-free metallation of porphyrins by ball milling with hydrated metal acetate salts for a few minutes with no added solvent; the products are then simply heated to remove the volatile acetic acid and water by-products. Normal methods for metallating porphyrins require solvents and heating to reflux, sometimes for long periods.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC02420C

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5. Low-Temperature Selective Catalytic Reduction (SCR) of NOx with n-Octane Using Solvent-Free Mechanochemically Prepared Ag/Al2O3 Catalysts

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