Synthesis of stable γ-phase MnS1−xSex nanoflakes with inversion symmetry breaking

Author:

Zheng Bo1ORCID,Fu Jun2,Zhu Yuanmin34,Liang Jing5,She Yongzhi6,Xiang Junxiang1,Ma Xiang1,Zhang Ying1,Wang Shasha1,Hu Guojing1,Zhou Yuehui1,Feng Yan1,Fu Zhengping1ORCID,Pan Nan6,Lu Yalin1,Zeng Hualing2,Gu Meng4,Liu Kaihui5,Xiang Bin1

Affiliation:

1. Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science & Engineering, CAS Key Lab of Materials for Energy Conversion, Anhui Laboratory of Advanced Photon Science and Technology, University of Science and Technology of China, Hefei, China

2. International Center for Quantum Design of Functional Materials (ICQD), Hefei National Laboratory for Physical Science at the Microscale, and Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, 230026, Hefei, Anhui, People's Republic of China

3. School of Materials Science and Engineering, Dongguan University of Technology, Dongguan, 523808, China

4. Department of Materials Science and Engineering, Southern University of Science and Technology China, Shenzhen, China

5. State Key Laboratory for Mesoscopic Physics, Frontiers Science Center for Nano-optoelectronics, School of Physics, Peking University, Beijing, China

6. Department of Physics, University of Science and Technology of China, Hefei 230026, China

Abstract

In this paper, we report the rational synthesis of stable γ-phase MnS1−xSex (0 ≤ x ≤ 0.45) nanoflakes. By tuning the parameters of synthesis duration and temperature, we produced a detailed growth phase diagram.

Funder

National Synchrotron Radiation Laboratory

Shenzhen Science and Technology Innovation Program

Guangdong Province Introduction of Innovative R&D Team

National Natural Science Foundation of China

Shenzhen Fundamental Research Program

USTC Center for Micro- and Nanoscale Research and Fabrication

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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