Rotameric transformations in the photochemistry of TpM(CO)2(η3-C3H4R), where Tp = tris(pyrazolyl)borate, M = Mo or W, and R = H or Me-Reference-Cited by-同舟云学术

Rotameric transformations in the photochemistry of TpM(CO)2(η3-C3H4R), where Tp = tris(pyrazolyl)borate, M = Mo or W, and R = H or Me

Published:2015 Issue:17 Volume:44 Page:8007-8012
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Thornley Wyatt A.¹²³⁴,Bitterwolf Thomas E.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Idaho

3. Moscow

4. USA

Abstract

Photolysis of the exo allyl rotamers of TpM(CO)₂(η³-C₃H₄R) complexes, where M = Mo or W, and R = 2-H or 2-Me, at 85 K results in reversible formation of the gauche allyl rotamer.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03940H

Reference30 articles.

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4. Thermal and photochemical interconversions of isomeric monocarbonyl η5-Cyclopentadienyl(η3-allyl)iron complexes

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