Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst-Reference-Cited by-同舟云学术

Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst

Published:2019 Issue:66 Volume:9 Page:38877-38881
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yuan Hangkong¹²³⁴⁵,Kusema Bright T.⁶⁷⁸⁵,Yan Zhen⁶⁷⁸⁵,Streiff Stéphane⁶⁷⁸⁵,Shi Feng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation

2. Lanzhou Institute of Chemical Physics (LICP)

3. Chinese Academy of Sciences

4. Lanzhou 730000

5. China

6. Eco-Efficient Products and Processes Laboratory (E2P2L)

7. UMI 3464 CNRS-Solvay

8. 201108 Shanghai

Abstract

A simple and highly efficient method was developed for one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) over bifunctional Cu₄Ni₁Al₄Ox catalyst using two-stage reaction process, affording the BAF in 85.9% yield.

Funder

National Natural Science Foundation of China

Youth Innovation Promotion Association

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA08560B

Reference24 articles.

1. E.Karsten , H.Erhard , R.Roland and H.Hartmut , Amines, Aliphatic in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH , Weinheim , 2005