Strength order and nature of the π-hole bond of cyanuric chloride and 1,3,5-triazine with halide-Reference-Cited by-同舟云学术

Strength order and nature of the π-hole bond of cyanuric chloride and 1,3,5-triazine with halide

Published:2015 Issue:32 Volume:17 Page:20636-20646
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Hui¹²³⁴,Li Chen¹²³⁴,Wang Weizhou⁵⁶⁷⁴,Jin Wei Jun¹²³⁴

Affiliation:

1. College of Chemistry

2. Beijing Normal University

3. Beijing 100875

4. P. R. China

5. College of Chemistry and Chemical Engineering

6. Luoyang Normal University

7. Luoyang 471022

Abstract

The 3ClN/3N⋯X⁻π-hole bond is electrostatically attractive in nature. In the gas phase, it follows the order 3ClN/3N⋯Cl⁻> 3ClN/3N⋯Br⁻> 3ClN/3N⋯I⁻. However, in solution the order is the reverse due to the solvation effect.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03076E

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