Theoretical study of hydroxyl radical (OH˙) induced decomposition of tert-butyl methyl ether (MTBE)

Author:

Tawabini Bassam S.12345,Nielsen Ole John6789ORCID,Sølling Theis I.1021145ORCID

Affiliation:

1. Department of Geosciences

2. College of Petroleum & Geosciences

3. King Fahad University of Petroleum & Minerals (KFUPM)

4. Dhahran 31261

5. Saudi Arabia

6. Department of Chemistry

7. University of Copenhagen

8. Copenhagen

9. Denmark

10. Center for Integrative Petroleum Research

11. King Fahad University of Petroleum & Minerals

Abstract

We have characterized the various pathways for OH radical (OH˙) induced decomposition of tert-butyl methyl ether (MTBE) and found an oxidative pathway that leads to complete degradation under the prerequisite that OH radicals are present in excess.

Funder

King Fahd University of Petroleum and Minerals

Publisher

Royal Society of Chemistry (RSC)

Subject

Management, Monitoring, Policy and Law,Public Health, Environmental and Occupational Health,Environmental Chemistry,General Medicine

Reference24 articles.

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2. USEPA Clean Air Act Amendments of 1990 , P.L. 101-549, 104 Stat. 2399, November 15, 1990

3. Methyl tert -Butyl Ether (MTBE) Contamination in Private Wells near Gasoline Stations in Upstate New York

4. Advanced oxidation and reduction process chemistry of methyl tert-butyl ether (MTBE) reaction intermediates in aqueous solution: 2-Methoxy-2-methyl-propanal, 2-methoxy-2-methyl-propanol, and 2-methoxy-2-methyl-propanoic acid

5. P. J. Squillace , D. A.Pope , and C. V.Price , Occurrence of the gasoline additive MTBE in shallow ground water in urban and agricultural areas , U.S. Geological Survey Fact Sheet FS-114-95 , 1995 , p. 4

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