Complexation of tetravalent uranium cations by the As4W40O140 cryptand-Reference-Cited by-同舟云学术

Complexation of tetravalent uranium cations by the As4W40O140 cryptand

Published:2018 Issue:37 Volume:20 Page:5500-5509
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Dufaye Maxime¹²³⁴⁵^ORCID,Duval Sylvain¹²³⁴⁵^ORCID,Hirsou Bastien¹²³⁴⁵,Stoclet Grégory⁶²³⁷⁸,Loiseau Thierry¹²³⁴⁵^ORCID

Affiliation:

1. Unité de Catalyse et Chimie du Solide (UCCS) – UMR CNRS 8181

2. Université de Lille

3. Centrale Lille

4. ENSCL

5. Univ. Artois

6. Unité Matériaux Et Transformations (UMET) – UMR CNRS 8207

7. F-59000 Lille

8. France

Abstract

The polyanionic cryptand {As₄W₄₀O₁₄₀} was successfully used to bind up to four tetravalent uranium cations leading to the formation of three new cryptates. The obtained species appears to be stable in solution and the cryptand was used for U^IV/Nd^III separation studies.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE00873F

Reference59 articles.

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