A valence tautomeric cobalt–dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides
Author:
Affiliation:
1. Friedrich-Alexander University Erlangen-Nürnberg (FAU)
2. Department of Chemistry and Pharmacy
3. Erlangen
4. Germany
Abstract
A valence tautomeric cobalt–dioxolene complex featuring a protected anchoring group has been synthesized and its thermal switchability has been confirmed.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03771K
Reference40 articles.
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2. Valence Tautomeric Transition Metal Complexes
3. Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands
4. Switchable cobalt coordination polymers: Spin crossover and valence tautomerism
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1. Low-spin to low-spin valence tautomeric transition in cobalt bis-dioxolenes;Dalton Transactions;2024
2. o-Benzoquinone Cobalt Complexes Bearing Organosilicon Radicals: Quantum-Chemical Study;Russian Journal of Coordination Chemistry;2022-04
3. Impact of Positional Isomers on the Selective Isolation of cis-trans Isomers in Cobalt-Dioxolene Chemistry and Solvation Effects on the Valence Tautomerism in the Solid State;Crystal Growth & Design;2021-12-31
4. Metallocomplexes, exhibiting catecholate binding mode for o-quinone, annulated with dithiete cycle;Inorganica Chimica Acta;2021-12
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