Visible-light-induced copper-catalyzed oxidative esterification of α-azidoketones with diazoacetates: access to α-acyloxyacetates-Reference-Cited by-同舟云学术

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Visible-light-induced copper-catalyzed oxidative esterification of α-azidoketones with diazoacetates: access to α-acyloxyacetates

Published:2024 Issue:26 Volume:22 Page:5414-5418
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Newar Uma Devi¹²,Boruah Dhruba Jyoti¹²,Bhuyan Arnav¹,Nayak Abhimanyu¹,Maurya Ram Awatar¹²^ORCID

Affiliation:

1. Applied Organic Chemistry Group, Chemical Sciences & Technology Division, CSIR-North East Institute of Science & Technology (NEIST), Jorhat-785006, Assam, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

Abstract

An efficient synthesis of α-acyloxyacetates from α-azidoketones and diazoacetates under visible light-Cu(OAc)2-DBU catalysis was demonstrated.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00590B

Reference49 articles.

1. Cefuroxime Axetil

2. Sultamicillin

3. The nucleophilic addition of α-metallated 1,3-dioxanes to planar chiral cationic η3-allylmolybdenum complexes. Synthesis of (2E,5S,6R,7E)-6-methyl-8-phenylocta-2,7-dienoic acid methyl ester, a key component of the Cryptophycins

4. Chemistry and Biology of Cyclic Depsipeptides of Medicinal and Biological Interest

5. Carboxylic Acid Functionalization Using Sulfoxonium Ylides as a Carbene Source

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