Zirconocene dichlorides as catalysts in alkene carbo- and cyclometalation by AlEt3: intermediate structures and dynamics-Reference-Cited by-同舟云学术

Zirconocene dichlorides as catalysts in alkene carbo- and cyclometalation by AlEt3: intermediate structures and dynamics

Published:2021 Issue:43 Volume:50 Page:15802-15820
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Parfenova Lyudmila V.¹^ORCID,Kovyazin Pavel V.¹,Mukhamadeeva Olesia V.¹,Ivchenko Pavel V.²³^ORCID,Nifant'ev Ilya E.²³,Khalilov Leonard M.¹^ORCID,Dzhemilev Usein M.¹

Affiliation:

1. Institute of Petrochemistry and Catalysis of Russian Academy of Sciences, prosp. Oktyabrya, 450075 Ufa, 141, Russian Federation

2. Department of Chemistry, Lomonosov Moscow State University, 1-3 Leninskiye Gory, 119991 Moscow, Russian Federation

3. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, 119991 Moscow, Russian Federation

Abstract

Catalytic activity and chemoselectivity of zirconocenes in the reaction of alkenes with AlEt3 were evaluated. NMR study of the reaction between L2ZrCl2 and AlEt3 showed the formation of various bimetallic intermediates.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03160K

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