A novel octa-nuclear 32-membered zirconocene macrocycle based on the aromatic selenite-Reference-Cited by-同舟云学术

A novel octa-nuclear 32-membered zirconocene macrocycle based on the aromatic selenite

Published:2017 Issue:2 Volume:46 Page:524-528
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yao Nian-Tao¹²³⁴,Zhang Ru-Fen¹²³⁴,Zhang Shao-Liang¹²³⁴,Li Qian-Li¹²³⁴,Ma Chun-Lin¹²³⁴

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Liaocheng University

3. Liaocheng

4. China

Abstract

A novel macrocyclic zirconocene(iv) aromatic selenite [(CpZr)₈L₁₆]·2(Cp₄Zr₂(μ-O)Cl₂) (complex 1) (Cp = cyclopentadienyl anion; L = 4-fluorobenzeneseleninic acid) was prepared by the reaction of bis(cyclopentadienyl)zirconium dichloride with 4-fluorobenzeneseleninic acid and characterized by elemental analysis, infrared spectroscopy, ¹H, ¹³C NMR spectroscopy, ESI-MS, XRD and X-ray diffraction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04061F

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