Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates-Reference-Cited by-同舟云学术

Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates

Published:2021 Issue:6 Volume:6 Page:1053-1069
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Edeleva Mariya¹²³⁴^ORCID,Marien Yoshi W.¹²³⁴^ORCID,Van Steenberge Paul H. M.¹²³⁴^ORCID,D'hooge Dagmar R.¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory for Chemical Technology (LCT)

2. Ghent University

3. 9052 Zwijnaarde

4. Belgium

5. Centre for Textile Science and Engineering (CTSE)

Abstract

Conventional batch solution free radical polymerization of n-butyl acrylate with thermal initiators such as AIBN is known to be strongly exothermic and influenced by highly activated side reactions such as backbiting and β-scission.

Funder

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RE/D1RE00099C

Reference112 articles.

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2. Heats of polymerization of acrylic acid and derivatives

3. Chapter 2. Heat of Polymerization

4. Controlled/living radical polymerization in aqueous dispersed systems

5. 4-Dimensional Modeling Strategy for an Improved Understanding of Miniemulsion NMP of Acrylates Initiated by SG1-Macroinitiator

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