Homocoupling versus reduction of radicals: an experimental and theoretical study of Ti(iii)-mediated deoxygenation of activated alcohols-Reference-Cited by-同舟云学术

Homocoupling versus reduction of radicals: an experimental and theoretical study of Ti(iii)-mediated deoxygenation of activated alcohols

Published:2015 Issue:11 Volume:13 Page:3462-3469
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Prieto Consuelo¹²³⁴,González Delgado José A.¹²³⁴,Arteaga Jesús F.⁵⁶⁷⁸⁹,Jaraíz Martín¹⁰¹¹¹²¹³⁴,López-Pérez José L.¹⁴¹⁵¹⁶⁴,Barrero Alejandro F.¹²³⁴

Affiliation:

1. Department of Organic Chemistry and Institute of Biotechnology

2. University of Granada

3. 18071 Granada

4. Spain

5. CIQSO – Center for Research in Sustainable Chemistry

6. and Department of Chemical Engineering

7. Physical Chemistry and Organic Chemistry

8. University of Huelva

9. 21071 Huelva

10. Department of Electronics

11. ETSIT

12. University of Valladolid

13. Valladolid

14. Department of Pharmaceutical Chemistry-IBSAL-CIETUS

15. University of Salamanca

16. 37071 Salamanca

Abstract

A detailed study corroborates that the Ti(iii)-mediated reductive deoxygenation of activated -OH proceeds via an allyl(benzyl)-radical and allyl(benzyl)-Ti, which is protonated, regioselectively in the case of allylic derivatives.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02290D

Reference31 articles.

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