Hydrosilylation and Mukaiyama aldol-type reaction of quinolines and hydrosilylation of imines catalyzed by a mesoionic carbene-stabilized borenium ion
Author:
Affiliation:
1. Department of Chemistry
2. Queen's University
3. Kingston
4. Canada
5. Division of Applied Chemistry
6. Institute of Transformative Bio-Molecules (WPI-ITbM)
Abstract
Aldimines and ketimines are hydrosilylated with borenium catalysts at room temperature, giving the corresponding amines in excellent yields. For quinolines, subsequent Mukaiyama aldol reactions can be performed, which are also borenium-ion catalyzed.
Funder
Natural Sciences and Engineering Research Council of Canada
Canada Foundation for Innovation
Queen's University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01056E
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5. Amine synthesis via transition metal homogeneous catalysed hydrosilylation
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