Pseudo enantiomeric mixed S/P ligands derived from carbohydrates for the 1,4-addition of phenyl boronic acid to cyclohexenone-Reference-Cited by-同舟云学术

Pseudo enantiomeric mixed S/P ligands derived from carbohydrates for the 1,4-addition of phenyl boronic acid to cyclohexenone

Published:2016 Issue:4 Volume:6 Page:3041-3047
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Valdivia V.¹²³⁴⁵,Bilbao N.¹²³⁴,Moya J. F.¹²³⁴,Rosales-Barrios C.¹²³⁴,Salvador A.¹²³⁴,Recio R.⁵⁶⁷⁴,Fernández I.⁵⁶⁷⁴,Khiar N.¹²³⁴

Affiliation:

1. Asymmetric Synthesis and Functional Nanosystem Group

2. Instituto de Investigaciones Químicas CSIC-Universidad de Sevilla

3. 41092 Seville

4. Spain

5. Departamento de Química Orgánica y Farmacéutica. Facultad de Farmacia

6. Universidad de Sevilla. C/Profesor García González 2

7. Seville

Abstract

Mixed S/P ligands 3 and 10, good catalyst precursors for the Rh(i)-catalysed 1,4-addition of phenylboronic acid to cyclohexenone behave as enantiomers even though both derived from d-sugars.

Funder

Consejo Superior de Investigaciones Científicas

Consejería Economía, Innovación, Ciencia y Empleo, Junta de Andalucia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA10181F

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