Affiliation:
1. Laboratory for Computational Molecular Design, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne 1015, Switzerland
Abstract
The π–π* transitions of disubstituted spiropentadiene become helical due to mixing of its two perpendicular π-systems. The helicity is symmetry-protected and gives rise to experimentally observable effects, such as optical activity.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Cited by
15 articles.
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