Copper(ii) complexes with 2,2′:6′,2′′-terpyridine, 2,6-di(thiazol-2-yl)pyridine and 2,6-di(pyrazin-2-yl)pyridine substituted with quinolines. Synthesis, structure, antiproliferative activity, and catalytic activity in the oxidation of alkanes and alcohols with peroxides-Reference-Cited by-同舟云学术

Copper(ii) complexes with 2,2′:6′,2′′-terpyridine, 2,6-di(thiazol-2-yl)pyridine and 2,6-di(pyrazin-2-yl)pyridine substituted with quinolines. Synthesis, structure, antiproliferative activity, and catalytic activity in the oxidation of alkanes and alcohols with peroxides

Published:2019 Issue:33 Volume:48 Page:12656-12673
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Choroba Katarzyna¹²³⁴^ORCID,Machura Barbara¹²³⁴^ORCID,Kula Slawomir¹²³⁴^ORCID,Raposo Luis R.⁵⁶⁷⁸⁹^ORCID,Fernandes Alexandra R.⁵⁶⁷⁸⁹^ORCID,Kruszynski Rafal¹⁰¹¹¹²⁴^ORCID,Erfurt Karol¹³¹⁴¹⁵⁴^ORCID,Shul'pina Lidia S.¹⁶¹⁷¹⁸¹⁹^ORCID,Kozlov Yuriy N.²⁰¹⁷¹⁸¹⁹¹⁶^ORCID,Shul'pin Georgiy B.²⁰¹⁷¹⁸¹⁹²¹^ORCID

Affiliation:

1. Institute of Chemistry

2. University of Silesia

3. 40-006 Katowice

4. Poland

5. UCIBIO

6. Departamento de Ciências da Vida

7. Faculdade de Ciências e Tecnologia

8. Universidade NOVA de Lisboa

9. 2829-516 Caparica

10. Institute of General and Ecological Chemistry

11. Lodz University of Technology

12. 90-924 Lodz

13. Department of Chemical Organic Technology and Petrochemistry

14. Silesian University of Technology

15. 44-100 Gliwice

16. Nesmeyanov Institute of Organoelement Compounds

17. Russian Academy of Sciences

18. Moscow 119991

19. Russia

20. Semenov Institute of Chemical Physics

21. Plekhanov Russian University of Economics

Abstract

The toxicity of six new Cu(ii) complexes was evaluated in cancer derived cell lines. A model of competitive interaction of hydroxyl radicals with CH₃CN and RH in the catalyst cavity has been proposed.

Funder

Russian Foundation for Basic Research

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01922G

Reference150 articles.

1. Copper Active Sites in Biology

2. Mechanism of O2 activation and substrate hydroxylation in noncoupled binuclear copper monooxygenases