Pyridine-di-phosphonates as chelators for trivalent f-elements: kinetics, thermodynamic and interfacial study of Am(iii)/Eu(iii) solvent extraction

Author:

Konopkina Ekaterina A.1ORCID,Matveev Petr I.1ORCID,Huang Pin-Wen2,Kirsanova Anna A.1,Chernysheva Maria G.1ORCID,Sumyanova Tsagana B.1,Domnikov Kirill S.1,Shi Wei-Qun3ORCID,Kalmykov Stepan N.1,Petrov Vladimir G.1ORCID,Borisova Nataliya E.1ORCID

Affiliation:

1. Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russian Federation

2. Zhejiang University of Water Resources and Electric Power, Hangzhou, 310018, China

3. Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

Abstract

We synthesized and studied four pyridine di-phosphonates as extractants selective for Am(iii).

Funder

Russian Science Foundation

National Science Fund for Distinguished Young Scholars

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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