Fluorinated click-derived tripodal ligands drive spin crossover in both iron(<scp>ii</scp>) and cobalt(<scp>ii</scp>) complexes-Reference-Cited by-同舟云学术

Fluorinated click-derived tripodal ligands drive spin crossover in both iron(ii) and cobalt(ii) complexes

Published:2022 Issue:27 Volume:51 Page:10507-10517
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nößler Maite¹,Hunger David²,Neuman Nicolás I.¹³⁴^ORCID,Reimann Marc⁵^ORCID,Reichert Felix²,Winkler Mario²,Klein Johannes¹,Bens Tobias³,Suntrup Lisa¹,Demeshko Serhiy⁶,Stubbe Jessica¹,Kaupp Martin⁵^ORCID,van Slageren Joris²,Sarkar Biprajit¹³^ORCID

Affiliation:

1. Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34-36, 14195, Berlin, Germany

2. Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

3. Lehrstuhl für Anorganische Koordinationschemie, Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

4. Instituto de Desarrollo Tecnológico para la Industria Química, INTEC, UNL-CONICET Paraje El Pozo, Santa Fe, Argentina

5. Institut für Theoretische Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany

6. Institut für Anorganische Chemie, Universität Göttingen, Tammanstraße 4, D-37077, Göttingen, Germany

Abstract

A fluorophenyl-substituted ligand drives complete and partial spin-crossover in Fe(ii) and Co(ii) complexes, respectively.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01005D

Reference81 articles.

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2. Thermal and light-induced spin crossover in iron(II) complexes

3. J. R.Gispert , Coordination Chemistry , Wiley-VCH , Weinheim, Germany , 2008

4. The nature of spin-state transitions in solid complexes of iron(II) and the interpretation of some associated phenomena